If you can actually HEAR the air escaping separate from (ie after) the sound of the shot you definitely have a problem with the valve hanging up.... Even with the lightest of valve springs, the air pressure should shut the valve with anything like 1000 psi in the gun.... I'm guessing maybe you bent the valve stem or it's got some dirt/chips making it drag.... On PCPs, I have found them to be relatively insensitive to valve spring changes, but VERY sensitive to hammer spring changes....Following the shot it sounds like i have a load of air traveling through the barrel after the pellet has left.
Bob